• Understand the significance of the atmosphere.
• Describe the composition of the atmospheric gasses.
• Explain the major layers of the atmosphere and their importance.
• Analyze the relationships between energy, temperature, and heat.
• Describe how the Sun influences seasonality.
• Describe how heat is transferred around the planet.

INTERACTION WITH SOLAR ENERGY

The diversity of earth’s surface is due to different concentrations of energy.  The atmosphere is the location of the first interaction of solar energy with the earth. About 40% of the earth’s total energy comes from the sun, the rest comes from within the earth.  The atmosphere is key for distribution and redistribution of this solar energy.

INDISPENSABLE FOR LIFE ON EARTH

Without the atmosphere, Earth would look a lot more like the Moon. Atmospheric gases, especially carbon dioxide (CO₂) and oxygen (O₂), are extremely important for living organisms. How does the atmosphere make life possible? How does life alter the atmosphere?

In photosynthesis plants use CO₂ and create O₂. Photosynthesis is responsible for nearly all of the oxygen currently found in the atmosphere. By creating oxygen and food, plants have made an environment that is favorable for animals. In respiration, animals use oxygen to convert sugar into food energy they can use. Plants also go through respiration and consume some of the sugars they produce.

The atmosphere has different properties at different elevations above sea level, or altitudes. The air density (the number of molecules in a given volume) decreases with increasing altitude. This is why people who climb tall mountains, such as Mt. Everest, have to set up camp at different elevations to let their bodies get used to the decreased air. Why does air density decrease with altitude? Gravity pulls the gas molecules towards Earth’s center. The pull of gravity is stronger closer to the center at sea level. Air is denser at sea level where the gravitational pull is greater. Gases at sea level are also compressed by the weight of the atmosphere above them. The force of the air weighing down over a unit of area is known as its atmospheric pressure. The reason why we are not crushed by this weight is because the molecules inside our bodies are pushing outward to compensate. Atmospheric pressure is felt from all directions, not just from above. At higher altitudes the atmospheric pressure is lower and the air is less dense than at higher altitudes. If your ears have ever “popped”, you have experienced a change in air pressure. Gas molecules are found inside and outside your ears. When you change altitude quickly, like when an airplane is descending, your inner ear keeps the density of molecules at the original altitude. Eventually the air molecules inside your ear suddenly move through a small tube in your ear to equalize the pressure. This sudden rush of air is felt as a popping sensation. Although the density of the atmosphere changes with altitude, the composition stays the same with altitude, with one exception. In the ozone layer, at about 20 km to 40 km above the surface, there is a greater concentration of ozone molecules than in other portions of the atmosphere.

The atmosphere is layered, corresponding with how the atmosphere’s temperature changes with altitude. By understanding the way temperature changes with altitude, we can learn a lot about how the atmosphere works. While weather takes place in the lower atmosphere, interesting things, such as the beautiful aurora, happen higher in the atmosphere. Why does warm air rise? Gas molecules are able to move freely and if they are free to move about, as they are in the atmosphere, they can take up more or less space.

• When gas molecules are cool, they are sluggish and do not take up as much space. With the same number of molecules in less space, both air density and air pressure are higher.
• When gas molecules are warm, they move vigorously and take up more space. Air density and air pressure are lower.

Warmer, lighter air is more buoyant than the cooler air above it, so it rises. The cooler air then sinks down, because it is denser than the air beneath it. This is convection, which was described in the Plate Tectonics chapter.

The property that changes most strikingly with altitude is air temperature. Unlike the change in pressure and density, which decrease with altitude, changes in air temperature are not regular. A change in temperature with distance is called a temperature gradient.

The atmosphere is divided into layers based on how the temperature in that layer changes with altitude, the layer’s temperature gradient. The temperature gradient of each layer is different. In some layers, temperature increases with altitude and in others it decreases. The temperature gradient in each layer is determined by the heat source of the layer. Most of the important processes of the atmosphere take place in the lowest two layers: the troposphere and the stratosphere.

TROPOSPHERE

• Over land at night or in winter when the ground is cold. The cold ground cools the air that sits above it, making this low layer of air denser than the air above it.
• Near the coast where cold seawater cools the air above it. When that denser air moves inland, it slides beneath the warmer air over the land.
• Since temperature inversions are stable, they often trap pollutants and produce unhealthy air conditions in cities. At the top of the troposphere is a thin layer in which the temperature does not change with height. This means that the cooler, denser air of the troposphere is trapped beneath the warmer, less dense air of the stratosphere. Air from the troposphere and stratosphere rarely mix.

In contrast to the troposphere, the stratosphere is calm and stable.  Air in the stratosphere is stable because warmer, less dense air sits over cooler, denser air. As a result, there is little mixing of air within the layer. Unlike the troposphere, the temperature in the stratosphere increases with increasing altitude. The stability in stratosphere is an advantage for pilots like to fly in the lower portions of the stratosphere because there is little air turbulence. But that same stability means that ash and gas from a large volcanic eruption may burst into the stratosphere, remains suspended there for many years.

The direct heat source for the stratosphere is radiation from the sun. The ozone layer is found within the stratosphere between 15 to 30 km (9 to 19 miles) altitude. The thickness of the ozone layer varies by the season and also by latitude. The ozone layer is extremely important because ozone gas in the stratosphere absorbs most of the sun’s ultraviolet (UV) radiation. As the high energy, shortwave UV radiation hits ozone molecules, some of the energy is transformed into low-energy, longwave heat and warms the stratosphere. Shortwave UV radiation is harmful to life. High-energy UV light penetrates cells and damages DNA, leading to cell death (which we know as a bad sunburn). Organisms on Earth are not adapted to heavy UV exposure, which kills or damages them. Without the ozone layer to reflect UV radiation, most complex life on Earth would not survive long.

ENERGY

Energy travels through space or material. This is obvious when you stand near a fire and feel its warmth or when you pick up the handle of a metal pot even though the handle is not sitting directly on the hot stove. Invisible energy waves can travel through air, glass, and even the vacuum of outer space. These waves have electrical and magnetic properties, so they are called electromagnetic waves. The transfer of energy from one object to another through electromagnetic waves is known as radiation. Different wavelengths of energy create different types of electromagnetic waves.

• The wavelengths humans can see are known as “visible light.” These wavelengths appear to us as the colors of the rainbow. What objects can you think of that radiate visible light? Two include the sun and a light bulb.
• The longest wavelengths of visible light appear red. Infrared wavelengths are longer than visible red. Snakes can see infrared energy. We feel infrared energy as heat.
• Wavelengths that are shorter than violet are called ultraviolet.

Can you think of some objects that appear to radiate visible light, but actually do not? The moon and the planets do not emit light of their own; they reflect the light of the sun. Reflection is when light (or another wave) bounces back from a surface. Albedo is a measure of how well a surface reflects light. A surface with high albedo reflects a large percentage of light. A snow field has high albedo.

One important fact to remember is that energy cannot be created or destroyed — it can only be changed from one form to another. This is such a fundamental fact of nature that it is a law: the law of conservation of energy.

In photosynthesis, for example, plants convert solar energy into chemical energy that they can use. They do not create new energy. When energy is transformed, some nearly always becomes heat. Heat transfers between materials easily, from warmer objects to cooler ones. If no more heat is added, eventually all of a material will reach the same temperature.

TEMPERATURE

Temperature is a measure of how fast the atoms in a material are vibrating. High temperature particles vibrate faster than low temperature particles. Rapidly vibrating atoms smash together, which generates heat. As a material cools down, the atoms vibrate more slowly and collide less frequently. As a result, they emit less heat. What is the difference between heat and temperature?

• Temperature measures how fast a material’s atoms are vibrating.
• Heat measures the material’s total energy.

Which has higher heat and which has higher temperature: a candle flame or a bathtub full of hot water?

• The flame has higher temperature, but less heat, because the hot region is very small.
• The bathtub has lower temperature but contains much more heat because it has many more vibrating atoms. The bathtub has greater total energy.

HEAT

Heat is taken in or released when an object changes state, or changes from a gas to a liquid, or a liquid to a solid. This heat is called latent heat. When a substance changes state, latent heat is released or absorbed. A substance that is changing its state of matter does not change temperature. All of the energy that is released or absorbed goes toward changing the material’s state.

For example, imagine a pot of boiling water on a stove burner: that water is at 100°C (212°F). If you increase the temperature of the burner, more heat enters the water. The water remains at its boiling temperature, but the additional energy goes into changing the water from liquid to gas. With more heat the water evaporates more rapidly. When water changes from a liquid to a gas it takes in heat. Since evaporation takes in heat, this is called evaporative cooling. Evaporative cooling is an inexpensive way to cool homes in hot, dry areas.

Humid air masses transport not just the water molecules but also the energy required to evaporate those air molecules. The energy required to evaporate 1 g of water already at 100°C to gaseous vapor at 100°C is 540 calories.  When that gaseous water condenses to liquid water, it releases 540 cal of energy to the immediate surroundings. For liquid water to freeze, it must release 80 cal.  Solid ice must gain 80cal to melt. Then definition of a calorie of energy is the amount of energy required to raise the temperature of 1g  water by 1°C from 3.5° to 4.5°C at standard air pressure. It is equivalent to 4.184 Joules of energy.

Substances also differ in their specific heat, the amount of energy needed to raise the temperature of one gram of the material by 1.0°C (1.8°F). Water has a very high specific heat, which means it takes a lot of energy to change the temperature of water. Let’s compare a puddle and asphalt, for example. If you are walking barefoot on a sunny day, which would you rather walk across, the shallow puddle or an asphalt parking lot? Because of its high specific heat, the water stays cooler than the asphalt, even though it receives the same amount of solar radiation.

The earth constantly tries to maintain an energy balance with the atmosphere. Most of the energy that reaches the Earth’s surface comes from the sun. About 44% of solar radiation is in the visible light wavelengths, but the sun also emits infrared, ultraviolet, and other wavelengths. When viewed together, all of the wavelengths of visible light appear white. But a prism or water droplets can break the white light into different wavelengths so that separate colors appear. Of the solar energy that reaches the outer atmosphere, UV wavelengths have the greatest energy. Only about 7% of solar radiation is in the UV wavelengths. The three types are:

• UVC: the highest energy ultraviolet, does not reach the planet’s surface at all.
• UVB: the second highest energy, is also mostly stopped in the atmosphere.
• UVA: the lowest energy, travels through the atmosphere to the ground.

The remaining solar radiation is the longest wavelength, infrared. Most objects radiate infrared energy, which we feel as heat. Some of the wavelengths of solar radiation traveling through the atmosphere may be lost because they are absorbed by various gases. Ozone completely removes UVC, most UVB and some UVA from incoming sunlight. Oxygen, carbon dioxide, and water vapor also filter out some wavelengths.

SOLAR RADIATION ON EARTH

Different parts of the Earth receive different amounts of solar radiation. Which part of the planet receives the most insolation? The sun’s rays strike the surface most directly at the equator. Different areas also receive different amounts of sunlight in different seasons. What causes the seasons? The seasons are caused by the direction Earth’s axis is pointing relative to the sun. The Earth revolves around the sun once each year and spins on its axis of rotation once each day. This axis of rotation is tilted 23.5 degrees relative to its plane of orbit around the sun. The axis of rotation is pointed toward Polaris, the North Star. As the Earth orbits the sun, the tilt of Earth’s axis stays lined up with the North Star.

Heat moves in the atmosphere the same way it moves through the solid Earth or another medium. What follows is a review of the way heat flows and is transferred, but applied to the atmosphere. Radiation is the transfer of energy between two objects by electromagnetic waves. Energy from the sun moves to the earth via radiation. Heat radiates from the ground into the lower atmosphere.

In conduction, heat moves from areas of more heat to areas of less heat by direct contact. Warmer molecules vibrate rapidly and collide with other nearby molecules, transferring their energy from one molecule to a different molecule. In the atmosphere, conduction is more effective at lower altitudes where air density is higher; transfers heat upward to where the molecules are spread further apart or transfers heat laterally from a warmer to a cooler spot, where the molecules are moving less vigorously.

Heat transfer by movement of heated materials is called convection. Heat that radiates from the ground initiates convection cells in the atmosphere.  Warm air molecules move to an area with less heat, bringing the heat energy with them.

HEAT AT EARTH’S SURFACE

About half of the solar radiation that strikes the top of the atmosphere is filtered out before it reaches the ground. This energy can be absorbed by atmospheric gases, reflected by clouds, or scattered. Scattering occurs when a light wave strikes a particle and bounces off in some other direction.

About 3% of the energy that strikes the ground is reflected back into the atmosphere. The rest is absorbed by rocks, soil, and water and then radiated back into the air as heat. These infrared wavelengths can only be seen by infrared sensors. Because solar energy continually enters Earth’s atmosphere and ground surface, is the planet getting hotter? The answer is no (although the next section contains an exception) because energy from Earth escapes into space through the top of the atmosphere. If the amount that exits is equal to the amount that comes in, then average global temperature stays the same. This means that the planet’s heat budget is in balance. What happens if more energy comes in than goes out? If more energy goes out than comes in?

To say that the Earth’s heat budget is balanced ignores an important point. The amount of incoming solar energy is different at different latitudes). Where do you think the most solar energy ends up and why? Where does the least solar energy end up and why? The difference in solar energy received at different latitudes drives atmospheric circulation.